Adhesion enhancement of powder coatings on galvanised steel by addition of organo-modified silica particles

摘要

The addition of organo-modified silica particles (OSP) to organic monolayer coatings has been investigated as an alternative to the use of primers or surface pretreatments in galvanised steel substrates. A commercial additive consisting of trifunctional organosilane (alkyl-triethoxysilane) grafted on silica particles was directly incorporated at different concentrations (1, 2.5, 3.5 and 4.5 wt%) as an integral additive in a polyester powder coating. The OSP were characterised physicochemically by means of FTIR and TGA, and the coating formulated by DSC. The anticorrosive properties of the systems were evaluated by means of electrochemical impedance spectroscopy (EIS), showing improvements with all the formulations containing the OSP, especially in the coating with 2.5% OSP. In order to explain this behaviour, morphological (using SEM) and adhesion studies were done. The formation of agglomerates in the powder coatings was detected when the concentration was over 2.5%. There was an improvement in the adhesion of the coating to the substrate for all the samples containing the OSP but especially for that containing 2.5%. The impact resistance was increased too, especially in the formulations with 2.5% and 3.5%.